The oxidative degradation of phenol <i>via in situ</i> H₂O₂ synthesis using Pd supported Fe-modified ZSM-5 catalysts

Stable Fe/ZSM-5 Nanosheet Zeolite Catalysts for the Oxidation of Benzene to Phenol

Fe/ZSM-5 nanosheet zeolites of varying thickness were synthesized with di- and tetraquaternary ammonium structure directing agents and extensively characterized for their textural, structural, and catalytic properties. Introduction of Fe3+ ions in the framework of nanosheet zeolites was slightly less effective than in bulk ZSM-5 zeolite. Steaming was necessary to activate all catalysts for N2O ...

single-step synthesis of multi-component spirobarbiturates using ionic liquids and synthesis of substituted pyridine filled with catalysts supported on solid substrate

in this thesis, a better reaction conditions for the synthesis of spirobarbiturates catalyzed by task-specific ionic liquid (2-hydroxy-n-(2-hydroxyethyl)-n,n-dimethylethanaminium formate), calcium hypochlorite ca(ocl)2 or n-bromosuccinimide (nbs) in the presence of water at room temperature by ultrasonic technique is provided. the design and synthesis of spirocycles is a challenging task becaus...

Continuous selective oxidation of methane to methanol over Cu - and Fe - modified ZSM - 5 catalysts in a flow reactor

The selective oxidation of methane to methanol is a key challenge in catalysis. Iron and copper modified ZSM-5 catalysts are shown to be effective for this reaction using H2O2 as the oxidant under continuous flow operation. Co-impregnation of ZSM-5 with Fe and Cu by chemical vapour impregnation yielded catalysts that showed high selectivity to methanol (> 92% selectivity, 0.5 % conversion), as ...

Azo-dye Orange II degradation by Fenton’s reaction using Fe/ZSM-5 zeolite as catalyst

This work deals with the non-biodegradable azo-dye Orange II degradation using the heterogeneous Fenton-like reaction using Fe/ZSM-5 zeolite as catalyst. The influence of some relevant parameters was studied, namely pH and temperature in the ranges 3.0 – 8.5 and 30 – 53 oC, respectively. Decolorization degree, TOC removal and leaching were evaluated along time in the experiments done. It was fo...

Dehydration of Methanol to Dimethyl Ether Employing Modified H-ZSM-5 Catalysts